AG Lüders

Abstract


Hg-BASED CUPRATES: MAGNETIC PROPERTIES, NMR AND NQR INVESTIGATIONS


The effect of excess oxygen on the superconducting properties of HgBa2CuO4+d is studied. Ac and dc magnetization measurements on well defined samples (d » 0.01 - 0.14) are performed. Analyzing the magnetization curves at T=5 K in different field regimes displays that TC, Bc1, the penetration depths and the absolute magnitude of the magnetization depend strongly on the oxygen content d. The maximum value of TC=96 K corresponds to d=0.08(1) which is equal to an average copper valence of v[Cu]=2.16. This value is significant for the in-plane Cu valence of optimally doped cuprates. Furthermore NMR and NQR techniques are applied on the Hg 1201 system.



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