AG Schwentner, FB Physik, Freie Universität Berlin

Penetration Depth of Photomobilized F Atoms in Ar Layers from a Sandwich Experiment

C. Bressler, M. Dickgießer, N. Schwentner

Institut für Experimentalphysik, FU Berlin, Arnimallee 14, 14195 Berlin, Germany

The mean value and the distribution of the penetration depth of F atoms is determined from samples composed of three layers with controlled thickness in the monolayer range and with a test of the compactness of the films via the intensity of surface excitons. F atoms with an average kinetic energy of 4.3 eV are generated in the top layer (Ar doped with F2) by photodissociation of F2 with 10.15 eV in a spin forbidden repulsive state. The F atoms are injected into an Ar spacer layer of variable thickness. Those reaching the interface to the Kr bottom layer are monitored via the intensity of the Kr2F fluorescence at a wavelength of 444 nm which allows to discriminate between F in Ar (439 nm), in Kr (453 nm) and at the Kr/Ar (444 nm) interface. The F content at the interface is kept below 1/20 of a monolayer to suppress recombination, and the detection sensitivity is increased to 1/1000 of a monolayer by excitation via Kr exciton energy transfer. The probability for F atoms to penetrate the Ar spacer layer decreases exponentially with increasing thickness down to 10% for a thickness of 23 monolayers, and an average penetration depth of 10 monolayers is derived. These very large penetration depths exceed those of F+ and F- ions by more than one order of magnitude. They are consistent with those molecular dynamics calculations which predict a rather rectilinear motion in channels of the Ar lattice. An average length of travel of up to 27 monolayers with a mean free path (large angle scattering) up to 4 monolayers is compatible with the results.

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